Create a custom toolbar

Step 1 - Open the Customize dialog
Choose View > Customize (or right-click in an empty area of the workspace and choose Customize from the context menu) to display the Customize dialog.
Step 2 - Select Toolbars tab
In the Customize dialog, select the Toolbars tab.
Step 3 - Enter new toolbar name
Click New. In the Toolbar Name dialog, enter a name for the new toolbar, and then click OK. The new, empty toolbar appears on the workspace. You may want to move it above or to the side of the Customize dialog so you can see it better.
Step 4 - Select the Commands tab
In the Customize dialog, select the Commands tab.
Step 5 - Select a menu
Under Categories on the left side, select a Menu (for example, File). Its items appear under Commands on the right side.
Step 6 - Drag icons into new toolbar
Drag the icons of the desired commands into the new toolbar.
Step 7 - Repeat until finished
Repeat steps 5 and 6 until your custom toolbar contains all the desired commands. Click Close to close the Customize dialog. Note that your new custom toolbar now appears in the list when you choose View > Toolbars.
Notes and Tips:
You can use this powerful feature to create toolbars customized for the type of work you do, providing one-click access to your most often used commands.
You can even add separator bars to your custom toolbar. To do so, display the Customize dialog as described above, and then right-click an icon in the new toolbar and choose Include Separator from the context menu.
You can add any command icon to any toolbar or menu simply by dragging in its icon as described in step 6 above.

Learn More:
Separate a tool from its flyout
Assign a keyboard shortcut - An example